I’m assuming that your NAS is transcoding to to WAV, or you ripped to WAV rather than FLAC in the first place. This would give your local stream a bit more of a jump in SQ.
If the Tidal album you are playing is an MQA version then it’s down on quality - see my comments in the “Tidal vs CD” thread. Sadly you can only see if it’s an MQA version in the Tidal desktop App.